Camın Çeşitli Sıvılar ile Islanabilirliği ve Kullanılan Temas Açısı Test Sıvılarının Serbest Yüzey Enerjisi Değerine Etkisi
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Abstract
Bu çalışmada camın, farklı sıvı damlaları ile yaptığı temas açılarına (θ) göre ıslanma davranışı değerlendirildi ve ayrıca kullanılan farklı test sıvı gruplarının damla θ verilerine bağlı serbest yüzey enerjisinin (SYE) hesaplanmasındaki etkisi detaylı olarak incelendi. Damla yayınım yöntemiyle gerçekleştirilen θ ölçümlerinde kullanılan polar test sıvıları su(S), gliserol(GL), formamit(F) ve etilen glikol(EG) iken, apolar test sıvıları ise diiodometan(D), bromonaftalin(B), dodekan(DOD)’dır. Camın SYE hesaplamasında Asit-Baz Yöntemi kullanıldı. Sonuç olarak, camın θ verilerine dayalı olarak asit-baz yöntemiyle belirlenen SYE değerinin, kullanılan test sıvılarının değişmesine bağlı olarak çok ciddi oranda değişebildiği ortaya konulmuştur.
Keywords
Abstract
In this study, the wetting behavior of a glass was evaluated according to the contact angles (θ) made with different liquid drops, and also the effect of different test liquid groups on the calculation of its surface free energy (SFE) depending on the drop θ data examined in detail. While the polar test liquids used in θ measurements performed by the drop diffusion method are water (W), glycerol (GL), formamide (F) and ethylene glycol (EG), the nonpolar test liquids are diiodomethane (D), bromonaphthalene (B), dodecane (DOD). ) is. The Acid-Base Method was used to calculate the SFE of the glass. As a result, it has been revealed that the SFE value of the glass can change very seriously depending on the change in the test liquids used.
Keywords
- [1] E.Y. Bormashenko, Wetting of Real Surfaces, Walter de Gruyter GmbH, Berlin, 2013.
- [1] E.Y. Bormashenko, Wetting of Real Surfaces, Walter de Gruyter GmbH, Berlin, 2013.
- [2] T. Young “An essay on the cohesion of liquids” Phil. Trans. Royal Society of London, 95, 65-87, 1805.[3] H. Y. Erbil, Surface Chemistry of Solid and Liquid Interfaces, Blackwell Publishing Ltd, Oxford, 2006.
- [4] P. Reynolds, Wetting of Surfaces in:Colloid Science (Principles, Methods and Applications) (Ed: T. Cosgrove), Blackwell Publishing Ltd., Oxford, 2005.
- [5]https://www.biolinscientific.com/measurements/surface-free-energy#what-is-surface-free-energy (23.05.2022)
- [6] J.N. Israelachvili, Intermolecular and Surface Forces. Academic Press Inc., San Diego, 1992.
- [7] R.J. Good, C.J. van Oss, The Modern Theory of Contact Angles and the Hydrogen Bond Components of SurfaceEnergies in: Modern Approaches to Wettability (Eds: M.E.Schrader and Loeb G.I.), Plenum Press, New York, 1992.
- [8] J. Leja, Surface Chemistry of Froth Flotation, Plenum Press, New York, 1982.
- [9] A. W. Adamson and A. P. Gast, Physical Chemistry of Surfaces, A Wıley, Interscience Puplication John Wiley & Sons Inc, New York, 1997.
- [10] A.Evcin, B.Ersoy, T.Uygunoğlu, İ.Güneş, “Farklı mineral katkıların epoksi zemin kaplama malzemesininıslanmazlığına ve yüzey enerjisine etkisi” Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 33:2, 581- 590, 2017.
- [11] J.Gregory “Fundamentals of flocculation” Critical Review in Environmental Control, Vol 19, Issue 3, 185- 230, 1989.
- [12] S. Lu, R. J. Pugh, E. Forssberg, Interfacial Separation of Particles, Elsevier B. V., Amsterdam, 2005.
- [13] L.A Dobrzanski, Engineering Materials and Materials Design, Fundamentals of Materials Science and Physical Metallurgy, WNT, Warsaw, 2006.
- [14] M. Zenkiewicz “Methods for the calculation of surface free energy of solids” Journal of Achievements in Materials and Manufacturing Engineering, 85, 46-55. 2007.
- [15]Atabek L.Ş., Karbon Fiber ve Elvaloy ile Takviyelendirilmiş Polipropilen/Poli(laktik asit) Karışımlarının Temas Açısı ve Islanabilirlik Özelliklerinin Araştırılması. Journal of Characterization, (1)3, 122-130, 2021.
- [16] B. Janczuk, T. Bialopiotrowicz, A.Zdziennicka “Some Remarks on the Components of the Liquid Surface Free Energy” Journal of Colloid and Interface Science, 211, 96-103, 1998.
- [18] E.Chibowski, R.Perea-Carpio “A novel method for surface free-energy determination of powdered solids” Journal of Colloid and Interface Sci., 240, 473-479, 2001.
- [19] L.P. Davila, S.H. Risbud, J.F.Shackelford, Quartz and Silicas in: Ceramic and Glass Materials (Structure, Properties and Processing) Eds: James F. Shackelford and Robert H. Doremus, Springer, NewYork, 2008.
- [20] X.Jing, Y.Xia, F.Chen, C.Yang, Z.Yang, S.H.I. Jaffery “Preparation of superhydrophobic glass surface withhigh adhesion” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 633, Article number 127681, 2021.
- [21] M. Rankl, S. Laib, S. Seeger “Surface tension properties of surface-coatings for application in biodiagnostics determined by contact angle measurements” Colloids and Surfaces B: Biointerfaces, 30, 177-186, 2003.
- [22] R. Belibel, C. Barbaud, L. Mora “Dynamic contact angle cycling homogenizes heterogeneous surfaces” Materials Science and Engineering C, 69, 1192-1200, 2016.
- [23] E.Pargoletti, L.Motta, V.Comite, P.Fermo, G.Cappelletti “The hydrophobicity modulation of glass andmarble materials by different Si-based coatings” Progress in Organic Coatings, 136, Article number 105260,[24] B.Nasilowska, K.Olkowicz, A.Bombalska “Surface morphology analysis and wettability of steel and glass modified with graphene oxide” Procedia Structural Integrity, 16, 230-236, 2019.
- [25] P.Hu, L.Liang, Y.Peng, H.Yu, G.Xie “Recovery of Microcrystalline Graphite from Quartz Using Magnetic Seeding” Minerals, 10, Article number 10010024, 2019.
- [26] A.Mabudia, M.Noaparasta, M.Gharabaghia, V.R.Vasquezb “A molecular dynamics study on the wettability of graphene-based silicon dioxide (glass) surface” Colloids and Surfaces A, 569, 43-51, 2019.
- [27] M.Xu, Y.Feng, Z.Li, X.Wang, C.Li, H.Jiang, Y. Chen “A novel, efficient and cost-effective synthesistechnique for the development of superhydrophobic glass surface” Journal of Alloys and Compounds, 781, 1175-[28] İ.Yıldırım, “Surface free energy characterization of powders” Ph.D. Thesis, Virginia Polytechnic Institute and State University, Virginia. 2001.
- [29] C.J. Van Oss, R.J.Good, M.K.Chaudhury “The role of van der waals forces and hydrogen bonds in“hydrophobic interactions between biopolymers and low energy surfaces” Journal of Colloid and Interface Science, Volume 111, Issue 2, 378-390, 1986.
- [30] H.J.Brusscher, Wettability of Surfaces in the Oral Cavity in: Modern Approaches to Wettability (Eds: M.E.Schrader and Loeb G.I.), Plenum Press, New York, 1992.
- [31] P.Ricco, N.C.Ramos, T.M.B.Campos, V.O.Soares, M.O.C.V.Boas, R.M.Melo “The roles of microstructureand surface energy on subcritical crack growth in glass-ceramics” Ceramics International, 47, 3827-6833, 2020.
